Nanoscale insight into C–C coupling on cobalt nanoparticles

descriptionPublicationkeyboard_double_arrow_right Article 14 Jul 2014 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 50, page 10,035 (issn: 1359-7345, eissn: 1364-548X,

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Authors: E A, Lewis; C J, Murphy; A, Pronschinske; M L, Liriano; E C H, Sykes;

doi: 10.1039/c4cc03678f

pmid: 25051314

Nanoscale insight into C–C coupling on cobalt nanoparticles

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Abstract

The Ullmann coupling of bromobenzene to biphenyl on Co nanoparticles proceeds below room temperature via an intermediate in which phenyl groups are bound directly to metallic Co. A similar surface-bound benzyl intermediate is observed for coupling of benzylbromide to bibenzyl on Co.

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