Platinum corroles

descriptionPublicationkeyboard_double_arrow_right Article 09 Jun 2014 Denmark, Norway English Publisher:Royal Society of Chemistry (RSC)Journal:Chem. Commun., volume 50, pages 11,093-11,096 (issn: 1359-7345, eissn: 1364-548X,

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Authors: Alemayehu, Abraham B.; Vazquez-Lima, Hugo; Beavers, Christine M.; Gagnon, Kevin J.; Bendix, Jesper; Ghosh, Abhik;

doi: 10.1039/c4cc02548b

pmid: 24911328

handle: 10037/25265 , 10037/7899

Platinum corroles

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Abstract

Platinum has been inserted into corroles for the first time and three oxidized Pt(IV)(corrole˙(2-))ArAr' complexes have been structurally characterized. The Soret maxima of these complexes exhibit an unusually strong dependence on the meso-aryl substituents on the corrole, indicating aryl → corrole˙(2-) charge transfer character in these transitions.

Countries

Denmark, Norway

Related Organizations

The Arctic University of Norway
Norway
Lawrence Berkeley National Laboratory
United States
University of Copenhagen
Denmark
University of Copenhagen
Denmark

Keywords

VDP::Mathematics and natural science: 400::Chemistry: 440::Inorganic chemistry: 442, VDP::Matematikk og Naturvitenskap: 400::Kjemi: 440::Uorganisk kjemi: 442

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