Lanthanide cation-templated synthesis of rotaxanes

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2013 United Kingdom English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 49, page 8,157 (issn: 1359-7345, eissn: 1364-548X,

Copyright policy )Funded by:EC | SUPRAIMAGINGMACHINES

Authors: Zapata, F; Blackburn, O; Langton, M; Faulkner, S; Beer, P;

doi: 10.1039/c3cc45404e

pmid: 23925587

Lanthanide cation-templated synthesis of rotaxanes

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Abstract

The first lanthanide cation-templated synthesis of an interlocked structure is demonstrated through an interpenetrated assembly between a pyridine N-oxide threading component coordinating to a lanthanide cation complexed within a macrocycle. Stoppering of the pseudo-rotaxane assembly allows for preparation of the [2]rotaxane.

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United Kingdom

Related Organizations

Chemistry Research Laboratory Department of Chemistry University of Oxford
United Kingdom
University of Oxford
United Kingdom
THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF OXFORD
United Kingdom

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