Hexagonal molecular “palladawheel”

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2013 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 49, page 8,042 (issn: 1359-7345, eissn: 1364-548X,

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Authors: Qi-Qiang, Wang; Victor W, Day; Kristin, Bowman-James;

doi: 10.1039/c3cc44714f

pmid: 23903807

Hexagonal molecular “palladawheel”

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Abstract

A hexagonal molecular "palladawheel" consisting of six N,N'-diphenyl-2,6-pyridinedicarboxamide-Pd(II) pincer complexes held together via six Pd∙∙∙O=CAmide bonds was efficiently synthesized and crystallographically characterized. The hexameric ring possesses C3 (pseudo-S6) symmetry with up-down alternating phenyl substituents acting as interior "spokes" and exterior "propellers."

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