New amido- and imido-titanium complexes

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1983 Netherlands English Publisher:Royal Society of Chemistry (RSC)Journal:Journal of the Chemical Society, Chemical Communications (issn: 0022-4936,

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Authors: Vroegop, Christina T.; Teuben, Jan H.; Bolhuis, Fré van; Linden, Johannes G.M. van der;

doi: 10.1039/c39830000550

handle: 11370/5cbe9128-4ab8-46cf-8b85-6584b2771573

New amido- and imido-titanium complexes

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Abstract

cpTiCl3 (cp = η5-C5H5) in reaction with Me3SiN(H)R (R = Et, Pri, But, or Ph) yields the amido complexes cpTi(Cl)2N(H)R, which react further by HCl abstraction to give the corresponding centrosymmetric binuclear imido complexes [cp(Cl)Ti]2(μ-RN)2; substitution of the chloride ligands by organic groups is possible with the imido complexes, as is reversible reduction to stable anionic complexes.

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Netherlands

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University of Groningen
Netherlands

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