
doi: 10.1039/c2pp25089f
pmid: 22580641
Irradiation of alkane-linked DNA hairpins possessing TTT steps with flanking purine bases yields products identified as the cis-syn (2 + 2) dimers formed between the central thymine and its 3'- and 5'-neighbors. Selective formation of the 3'-dimer is attributed to ground state conformational effects and electron transfer quenching by purine bases.
Electron Transport, Isomerism, Pyrimidine Dimers, Ultraviolet Rays, Inverted Repeat Sequences, Quantum Theory, DNA, Thymine
Electron Transport, Isomerism, Pyrimidine Dimers, Ultraviolet Rays, Inverted Repeat Sequences, Quantum Theory, DNA, Thymine
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