
A photoactivatable caged cyanide, 1-(2-nitrophenyl)ethyl (NPE) cyanide, was synthesized, which upon irradiation in the near UV releases cyanide. It is demonstrated that the compound can be used to induce formation of the Fe(III)-CN(-) complex in the heme protein nitrophorin 4 from Rhodnius prolixus.
Hemeproteins, Cyanides, Coordination Complexes, Ultraviolet Rays, Rhodnius, 610, Animals, Salivary Proteins and Peptides, Ferric Compounds, Recombinant Proteins
Hemeproteins, Cyanides, Coordination Complexes, Ultraviolet Rays, Rhodnius, 610, Animals, Salivary Proteins and Peptides, Ferric Compounds, Recombinant Proteins
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