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An efficient dehydroxymethylation reaction by a palladium catalyst

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2013 India English Publisher:Royal Society of Chemistry (RSC)Journal:Chem. Commun., volume 49, pages 252-254 (issn: 1359-7345, eissn: 1364-548X, Copyright policy )
Authors: MODAK, A; NAVEEN, T; MAITI, D;

doi: 10.1039/c2cc36951f

pmid: 23164948

An efficient dehydroxymethylation reaction by a palladium catalyst

Abstract

A general method for selective dehydroxymethylation has been discovered by using widely available Pd(OAc)(2). The present study offers a new synthetic strategy for the regioselective functionalization by employing the steric, electronic and coordinating nature of the hydroxymethyl (-CH(2)OH) group temporarily.

Country
India
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Keywords

Reductive Cleavage, Aldehydes, Alcohol Oxidation, Bonds, Molecular-Oxygen, Decarbonylation, Dna, Hydrogen-Production, Aryl Ethers, Aerobic Oxidation

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
45
Top 10%
Top 10%
Top 10%
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