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A C84 selective porphyrin macrocycle with an adaptable cavity constructed through alkyne metathesis

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2012 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 48, page 6,172 (issn: 1359-7345, eissn: 1364-548X, Copyright policy )
Authors: Chenxi, Zhang; Hai, Long; Wei, Zhang;

doi: 10.1039/c2cc32571c

pmid: 22588578

A C84 selective porphyrin macrocycle with an adaptable cavity constructed through alkyne metathesis

Abstract

A bisporphyrin macrocycle was constructed from a porphyrin-based diyne monomer in one step through alkyne metathesis. The fullerene binding studies (C(60), C(70) and C(84)) showed the highest binding affinity of the macrocycle for C(84), which is in great contrast to its bisporphyrin four-armed cage analogue that showed the strongest binding with C(70).

Related Organizations
Keywords

Models, Molecular, Macrocyclic Compounds, Porphyrins, Molecular Structure, Alkynes, Fullerenes

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
47
Top 10%
Top 10%
Top 10%
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