The conformational locking of asparagine

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2012 Spain English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 48, page 5,934 (issn: 1359-7345, eissn: 1364-548X,

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Authors: Cabezas, Carlos; Varela, Marcelino; Peña, Isabel; Mata, Santiago; López, Juan C.; Alonso, José L.;

doi: 10.1039/c2cc32109b , 10.5281/zenodo.14711736 , 10.5281/zenodo.14711737

pmid: 22573205

handle: 10261/376153

The conformational locking of asparagine

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Abstract

One dominant structure has been identified analysing the rotational spectrum of asparagine in sharp contrast with the multiconformational behaviour for other amino acids with polar side chains. This locking of the conformational variety to a single conformer has been ascribed to an intramolecular hydrogen bonding network involving α-amine, α-carboxylic and amide groups.

Country

Spain

Related Organizations

Spanish National Research Council
Spain
University of Valladolid
Spain

Keywords

Fourier Analysis, Lasers, Spectrum Analysis, Molecular Conformation, Hydrogen Bonding, Asparagine, Microwaves

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