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Amido analogues of zincocenes and cadmocenes

Authors: Graeme J. Moxey; Rhiannon S. Moorhouse; Jonathan McMaster; William Lewis; Alexander J. Blake; Deborah L. Kays;

Amido analogues of zincocenes and cadmocenes

Abstract

The synthesis and characterisation of low-coordinate zinc and cadmium complexes of the sterically demanding 1,3,6,8-tetra-tert-butylcarbazol-9-yl ligand ((t)Bu(4)carb(-)) are reported. ((t)Bu(4)carb)(2)M (M = Zn 1; M = Cd 2) are the first examples of formally two-coordinate bis-carbazol-9-yl complexes of the Group 12 metals and 2 is the first crystallographically characterised two-coordinate amido complex of cadmium. The structure and bonding within these complexes are explored via a combination of X-ray crystallography and DFT calculations. The solid state structures for these zinc and cadmium complexes differ greatly from each other; not only do the steric demands of the peripheral tert-butyl substituents in these systems act to inhibit solvent coordination, but they also influence the coordination geometry around the metal centres.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
16
Average
Average
Top 10%
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