Correlating Pt–P bond lengths and Pt–P coupling constants
Copyright policy )Correlating Pt–P bond lengths and Pt–P coupling constants
The X-ray structures of () cis-PtBr(2)(P(OMe)(3))(2), () cis-PtBr(2)(P(OMe)(2)Ph)(2), () cis-PtBr(2)(P(OMe)Ph(2))(2), () cis-PtBr(2)(PPh(3))(2), () cis-PtI(2)(P(OMe)(3))(2), () cis-PtI(2)(P(OMe)(2)Ph)(2), () cis-PtI(2)(P(OMe)Ph(2))(2) and () cis-PtI(2)(PPh(3))(2) are reported and compared with the previously reported chloride analogues. The magnitude of the J{Pt-P} varies linearly with the Pt-P bond length (l(Pt-P) = 2.421 -J/24255) for these 12 complexes.
- Newcastle University United Kingdom
- University of St Andrews United Kingdom
Crystal-structures, Stacking compounds, Phosphorus ligands, Molecular Conformation, 610, Nuclear-magnetic-resonance, Phosphorus, 540, Transition-metal-complexes, Molecular-structure, QD Chemistry, Crystallography, X-Ray, Solid-state structures, X-ray-structure, Coordination Complexes, QD, Tertiary phosphine complexes, Platinum(ii) complexes, Platinum
Crystal-structures, Stacking compounds, Phosphorus ligands, Molecular Conformation, 610, Nuclear-magnetic-resonance, Phosphorus, 540, Transition-metal-complexes, Molecular-structure, QD Chemistry, Crystallography, X-Ray, Solid-state structures, X-ray-structure, Coordination Complexes, QD, Tertiary phosphine complexes, Platinum(ii) complexes, Platinum
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