Powered by OpenAIRE graph
Found an issue? Give us feedback
addClaim

Polymer organogelators that make supramolecular organogels through physical cross-linking and self-assembly

Authors: Masahiro, Suzuki; Kenji, Hanabusa;

Polymer organogelators that make supramolecular organogels through physical cross-linking and self-assembly

Abstract

This tutorial review highlights recent and current advances in polymer organogelators, which are rare compared with low molecular weight gelators. In this review, we classify polymer organogelators in three categories: the formation of supramolecular crosslinking points by conformational changes, the addition of crosslinking agents and the self-assembly of gelation-causing segments. Highly stereoregular polymers form a physical gel in organic solvents, involving conformational changes such as helix formation. The addition of cross-linking agents into polymer solutions provides stimuli-sensitive organogels. Furthermore, polymer organogelators, which consist of versatile polymers, such as poly(ethylene glycol)s, polycarbonates, polyesters, polycaprolactones, polyolefins and low molecular weight gelators, function as good organogelators that can form organogels in many organic solvents at low concentration. The organogelation properties of polymer organogelators are significantly affected by the chemical structures of the introduced low molecular weight gelators and polymer backbones, the molecular weight of the polymer backbones and the linking mode between the low molecular weight gelator segment and the polymer.

Related Organizations
  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    208
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 1%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 1%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 1%
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
208
Top 1%
Top 1%
Top 1%
Upload OA version
Are you the author of this publication? Upload your Open Access version to Zenodo!
It’s fast and easy, just two clicks!