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Bio-inspired polyene cyclization: aziridinyl polyene cyclization catalyzed by InBr3

Authors: Yu-Jun, Zhao; Li-Jun Serena, Tan; Bin, Li; Si-Min, Li; Teck-Peng, Loh;

Bio-inspired polyene cyclization: aziridinyl polyene cyclization catalyzed by InBr3

Abstract

This communication describes a highly efficient aziridinyl polyolefin cyclization catalyzed by InBr(3) to synthesize chiral terpenoid bearing a 3-amino group in the A ring; both good yields and excellent asymmetric induction were achieved.

Related Organizations
Keywords

Biomimetics, Cyclization, Terpenes, Aziridines, Stereoisomerism, Polyenes, Indium, Catalysis, Substrate Specificity

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    influence
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Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
20
Average
Top 10%
Top 10%
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