Crystal structures of the HCl salts of pseudopeptidic macrocycles display “knobs into holes” hydrophobic interactions between aliphatic side chains

descriptionPublicationkeyboard_double_arrow_right Article , Other ORP type 01 Jan 2009 Spain English Publisher:Royal Society of Chemistry (RSC)Journal:CrystEngComm, volume 11, page 735 (eissn: 1466-8033,

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Authors: Alfonso Rodríguez, Ignacio; Bolte, Michael; Bru Roig, Miriam; Burguete, M. Isabel; Luis, Santiago V.;

doi: 10.1039/b821772f

handle: 10234/22733

Crystal structures of the HCl salts of pseudopeptidic macrocycles display “knobs into holes” hydrophobic interactions between aliphatic side chains

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Abstract

The crystal structures of three HCl salts of pseudopeptidic macrocycles show a H-bonding tubular stack of the rings, where the amino acidic side chains (Val, Leu, Ile) display an inter-columnar “knobs into holes” hydrophobic interaction pattern

Country

Spain

Related Organizations

Jaume I University
Spain
Institute of Advanced Chemistry of Catalonia
Spain
Spanish National Research Council
Spain
Goethe University Frankfurt
Germany

Keywords

HCI salts, Hydrophobic interaction

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