Organocatalytic asymmetric ring-opening of aziridines

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2008 English Publisher:Royal Society of Chemistry (RSC)Journal:Organic & Biomolecular Chemistry, volume 6, page 3,467 (issn: 1477-0520, eissn: 1477-0539,

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Authors: Paixao, Marcio Weber; Nielsen, Martin; Jacobsen, Christian Borch; Jørgensen, Karl Anker;

doi: 10.1039/b812369a

pmid: 19082146

Organocatalytic asymmetric ring-opening of aziridines

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Abstract

The organocatalytic ring-opening of N-tosyl protected aziridines by beta-ketoesters under chiral PTC-conditions, leading to the formation of optically active aminoethyl functionalised compounds with up to 99% ee, has been developed.

Related Organizations

National Research Foundation
South Africa
Danish National Research Foundation
Denmark
Aarhus University
Denmark

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