Ring expansions and contractions of metalloporphyrins

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2008 English Publisher:Royal Society of Chemistry (RSC)Journal:Dalton Transactions (issn: 1477-9226, eissn: 1477-9234,

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Authors: Henry J, Callot;

doi: 10.1039/b807066k

pmid: 19002318

Ring expansions and contractions of metalloporphyrins

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Abstract

Ring expansions or contractions of metalloporphyrins are unusual reactions. In this review, the author will show how the step by step analysis of two serendipitous reactions allows one to unveil their mechanism and to point out the key role of nickel ion in these rearrangements.

Related Organizations

Institut de Chimie
France
UNIVERSITE MARIE ET LOUIS PASTEUR
France

Keywords

Models, Molecular, Porphyrins, Metalloporphyrins, Nickel, Nitrogen, Indicators and Reagents

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