Uranyl stabilized Schiff base complex

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2007 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications (issn: 1359-7345, eissn: 1364-548X,

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Authors: Mohan S, Bharara; Stephen A, Tonks; Anne E V, Gorden;

doi: 10.1039/b712322a

pmid: 17912397

Uranyl stabilized Schiff base complex

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Abstract

Uranyl Schiff base complex [(UO(2))(2)(Salpro)(OH)(Solvent)(2)] (1) in the presence of excess of ethylenediamine (EDA) does not undergo nucleophilic addition (hydrolysis) and substitution (transamination) reactions due to an extended chelation [2N, 3O + OH] by the flexible backbone.

Related Organizations

Auburn University System
United States
Auburn University
United States

Keywords

Models, Molecular, Molecular Structure, Spectrophotometry, Solvents, Crystallography, X-Ray, Uranium Compounds, Schiff Bases

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