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</script>doi: 10.1039/b706712g
pmid: 18004416
We investigate the photochemistry and photodissociation dynamics of uracil by two-colour photofragment Doppler spectroscopy and by two-colour slice imaging at excitation wavelengths between 268 and 235 nm. We observe the loss of a hydrogen atom upon excitation into the pipi* state. The angular distribution indicates a statistical process, while the translational energy distribution agrees with a dissociation that takes place on the electronic ground state. The pipi* state most likely deactivates via the lower-lying npi* state. In addition there is evidence for a second pathway: direct decay of the pipi* state to the electronic ground state with subsequent dissociation. Experiments on uracil-1,3-D(2) show that there is no site selectivity in the dissociation process. No evidence was found for the direct dissociation via a pisigma* excited state that seems to be relevant in the photochemistry of adenine and many other heterocyclic molecules. Overall, the photochemistry of uracil is similar to that of thymine.
Kinetics, Photolysis, Energy Transfer, Heterocyclic Compounds, Photochemistry, Thermodynamics, Uracil, Mass Spectrometry, Thymine
Kinetics, Photolysis, Energy Transfer, Heterocyclic Compounds, Photochemistry, Thermodynamics, Uracil, Mass Spectrometry, Thymine
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