Dicarba-closo-dodecaborane(12) derivatives of phosphonium salts: easy formation of nido-carborane phosphonium zwitterions
Copyright policy )Dicarba-closo-dodecaborane(12) derivatives of phosphonium salts: easy formation of nido-carborane phosphonium zwitterions
The first examples of arylphosphonium salts containing a dicarba-closo-dodecaborane(12) (closo-carborane) are reported; in contrast to the 1,12-carborane derivative, the 1,2- and 1,7-isomers undergo a facile deboronation reaction in polar solvents to afford the corresponding nido-carborane phosphonium zwitterions.
- University of Sydney Australia
- University of Queensland Australia
- University of Queensland Australia
Boron Compounds, Diagnostic Imaging, Carcinoma cells, Carboxylic Acids, Molecular Conformation, Ligands, Structural characterization, Delocalized lipophilic cations, Organophosphorus Compounds, Isomerism, Neoplasms, Salts, Neutron capture therapy
Boron Compounds, Diagnostic Imaging, Carcinoma cells, Carboxylic Acids, Molecular Conformation, Ligands, Structural characterization, Delocalized lipophilic cations, Organophosphorus Compounds, Isomerism, Neoplasms, Salts, Neutron capture therapy
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