Kinetic and thermodynamic parameters for the equilibrium reactions of phenols with the dpph? radical

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2006 Italy English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications (issn: 1359-7345, eissn: 1364-548X,

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Authors: Foti M C; Daquino C;

doi: 10.1039/b606322e

pmid: 17028760

handle: 20.500.14243/158121

Kinetic and thermodynamic parameters for the equilibrium reactions of phenols with the dpph? radical

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Abstract

The kinetics and energetics of the reversible reaction of phenols with the dpph. radical have been studied; steric shielding of the divalent N by the o-NO2 in dpph. seems to be the main cause of the entropic barriers of this reaction.

Country

Italy

Related Organizations

National Research Council
Italy
Istituto di Chimica Biomolecolare
Italy
Institute of Communication and Computer Systems
Greece

Keywords

Kinetics, Hydrazines, Free Radicals, Molecular Structure, Phenols, Picrates, Biphenyl Compounds, Hexanes, Thermodynamics

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