Photooxidation of Co-thiolato complexes in protic and aprotic solvents

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2006 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications (issn: 1359-7345, eissn: 1364-548X,

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Authors: Billy, Hernandez; Yanju, Wang; Dong, Zhang; Matthias, Selke;

doi: 10.1039/b514601a

pmid: 16491188

Photooxidation of Co-thiolato complexes in protic and aprotic solvents

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Abstract

Protic solvents decrease the susceptibility of the thiolate ligand in Co(III) thiolato complexes toward attack by singlet oxygen, but greatly increase the conversion of the peroxidic intermediate to the sulfenato product.

Related Organizations

California State University Los Angeles
United States

Keywords

Oxygen, Molecular Structure, Photochemistry, Solvents, Cobalt, Sulfhydryl Compounds, Protons, Oxidation-Reduction

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