
doi: 10.1039/b505703e
pmid: 16189598
A new solid material has been created in ultra high vacuum by utilizing the aggregation process of C58 molecules deposited onto highly oriented pyrolytic graphite from a mass selected low-energy ion beam comprising C58+. Cluster fluxes of up to 3x10(11) ions s-1 cm-2 with impinging kinetic energies of 6+/-0.5 eV were typically applied. Growth of the solid C58 phase proceeds according to the cluster-aggregation-based Volmer-Weber scenario where initially ramified 2D islands transform into 3D pyramid-like structures at higher coverages. The C58 films created exhibit much higher thermal stability than the C60 solid phase. Sublimation of C58 sets in at a temperature of 700 K. Ultraviolet photoionization spectra (He I, 21.2 eV) yield a molecular ionization potential in the range between 6.6 and 7 eV. Density functional and Hartree-Fock theories suggest that the formation of C58 dimers and higher multimers upon deposition/aggregation gives rise to the high thermal stability and unique electronic properties of this material.
Kinetics, Spectrophotometry, Biomedical Engineering, Temperature, Graphite, Fullerenes, Electronics, Microscopy, Atomic Force, Dimerization
Kinetics, Spectrophotometry, Biomedical Engineering, Temperature, Graphite, Fullerenes, Electronics, Microscopy, Atomic Force, Dimerization
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