A bidentate borane as colorimetric fluoride ion sensor

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 01 Jan 2004 English Publisher:Royal Society of Chemistry (RSC)Journal:Chem. Commun. (issn: 1359-7345, eissn: 1364-548X,

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Authors: Stephané, Solé; François P, Gabbaï;

doi: 10.1039/b403596h , 10.1002/chin.200444242

pmid: 15154038

A bidentate borane as colorimetric fluoride ion sensor

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Abstract

The bright yellow bidentate diborane (3), obtained by reaction of 10-bromo-9-thia-10-boraanthracene (1) with dimesityl-1,8-naphthalenediylborate (2), serves as a colorimetric anion sensor and selectively complexes fluoride with an association constant greater than 5 × 109 M−1 in THF.

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