Cytosine-substituted metalloporphyrins: receptors for recognition of nucleotides in ion-selective electrodes
Copyright policy )Cytosine-substituted metalloporphyrins: receptors for recognition of nucleotides in ion-selective electrodes
A new series of cytosine-substituted metalloporphyrin conjugates (containing Co(II) and Zn(II) as the coordinated metals) were designed and investigated as nucleotide receptors in PVC-membrane-based ion-selective electrodes under neutral conditions. The potentiometric results indicate that these systems, in particular the Co(II)-containing complex, may be potentially useful sensors for complementary nucleotide substrates in the presence of 10 mol% tridodecylmethylammonium chloride (K(Pot.)(5'-GMP/5'-AMP)= 0.045).
- The University of Texas at Austin United States
- University of Chemistry and Technology Czech Republic
Ions, Quaternary Ammonium Compounds, Cytosine, Molecular Structure, Metalloporphyrins, Nucleotides, Potentiometry, Biosensing Techniques, Polyvinyl Chloride, Electrodes
Ions, Quaternary Ammonium Compounds, Cytosine, Molecular Structure, Metalloporphyrins, Nucleotides, Potentiometry, Biosensing Techniques, Polyvinyl Chloride, Electrodes
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