Spontaneous assembly of a hydrogen-bonded tetrahedron

descriptionPublicationkeyboard_double_arrow_right Article 10 Sep 2002Embargo end date: 26 Apr 2024 United States Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications (issn: 1359-7345, eissn: 1364-548X,

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Authors: Field, JE; Combariza, MY; Vachet, RW; Venkataraman, D;

doi: 10.1039/b207026j , 10.7275/5817

pmid: 12398006

Spontaneous assembly of a hydrogen-bonded tetrahedron

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Abstract

Triphenylamine ortho-tricarboxylic acid (1) has been synthesized and the crystal structure reported. This molecule is shown to spontaneously self-assemble into a hydrogen-bonded tetrahedron. Furthermore, Electrospray Ionization Mass Spectroscopy shows evidence for the stability of such aggregates from an ethanol/water solution.

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University of Massachusetts Amherst
United States
University of Massachusetts System
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