Piano-stool inversion in arene complexes of Ru(ii): modelling the transition state
Copyright policy )Piano-stool inversion in arene complexes of Ru(ii): modelling the transition state
In the solid-state, the [RuH(arene)(Binap)]CF3SO3, complexes, 1, arene = η6-benzene and 2, arene = η6-toluene, distort markedly from a classical three-legged piano-stool structure with the former having the P–Ru–P plane approximately perpendicular to the plane of the arene; this structure for 1 is what one would expect for a transition state leading from one diastereomer to another via inversion at ruthenium.
- University of Milan Italy
- Laboratory of Inorganic Chemistry Switzerland
chloride subtitution-reactions; enantioselective hydrogenation; asymmetric hydrogenation; crystal-structures; meo-biphep; X-ray; ruthenium; 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl; diastereoselectivity; intermediate
chloride subtitution-reactions; enantioselective hydrogenation; asymmetric hydrogenation; crystal-structures; meo-biphep; X-ray; ruthenium; 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl; diastereoselectivity; intermediate
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