Nickel mediated sulfur–selenium and sulfur–sulfur bond formation

Chia-Huei Lai; Joseph H. Reibenspies; Marcetta Y. Darensbourg

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Chemical Communicati...arrow_drop_down

Chemical Communications

Article . 1999 . Peer-reviewed

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https://dx.doi.org/10.1039/a90...

Article

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Nickel mediated sulfur–selenium and sulfur–sulfur bond formation

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1999Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications (issn: 1359-7345, eissn: 1364-548X,

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Authors: Chia-Huei Lai; Joseph H. Reibenspies; Marcetta Y. Darensbourg;

doi: 10.1039/a903973b

Nickel mediated sulfur–selenium and sulfur–sulfur bond formation

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Abstract

Electrophilic addition of the PhSeCl to a nickel dithiolate yields S,S′-bis(phenylselenenyl-N,N′-bis(mercaptoethyl)-1,5-diazacyclooctane nickel(II) dichloride and a dimeric, intermolecular bis-disulfide which results from ligand oxidation.

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