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Complexes of platinum(II) and palladium(II) with aminomethylphosphonic acid and glycylaminomethylphosphonic acid

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1997Publisher:Royal Society of Chemistry (RSC)Journal:Journal of the Chemical Society, Dalton Transactions (issn: 0300-9246, eissn: 1364-5447, Copyright policy )
Authors: Leoš Bláha; Ivan Lukeš; Jan Rohovec; Petr Hermann;

doi: 10.1039/a607736f

Complexes of platinum(II) and palladium(II) with aminomethylphosphonic acid and glycylaminomethylphosphonic acid

Abstract

The complexing properties of aminomethylphosphonic acid, Gly-(P), and glycylaminomethylphosphonic acid, Gly-Gly-(P), with Pt II and Pd II were investigated pH-metrically at 25 °C and at an ionic strength of 0.1 mol dm -3 (KNO 3 ) using ‘out of cell’ titrations. The stability constants calculated indicate formation of complexes with a metal∶ligand molar ratio of 1∶1 and 1∶2. The species and their distribution determined pH-metrically were confirmed by 31 P and 1 H NMR titrations. Comparison of our results for Gly-(P) and Gly-Gly-(P) with those for glycine and glycylglycine and other common dipeptides shows that the complexing properties of Pd II and Pt II towards both types are very similar.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
14
Average
Average
Average
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