Ruthenium maltolato complexes

Michael D. Fryzuk; Michael J. Jonker; Steven J. Rettig

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Chemical Communicati...arrow_drop_down

Chemical Communications

Article . 1997 . Peer-reviewed

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https://dx.doi.org/10.1039/a60...

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Ruthenium maltolato complexes

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1997Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications (issn: 1359-7345, eissn: 1364-548X,

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Authors: Michael D. Fryzuk; Michael J. Jonker; Steven J. Rettig;

doi: 10.1039/a606961d

Ruthenium maltolato complexes

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Abstract

Two maltol molecules can be deprotonated and coordinated to Ru II to generate a series of octahedral complexes having the general formula Ru(ma) 2 L 2 (ma = C 6 H 5 O 3 ; L = PPh 3 , Me 2 SO; L 2 = cycloocta-1,5-diene); when L = PPh 3 , a precursor for the dimerization of phenylacetylene is obtained.

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