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Local non-equilibrium thermodynamics

Authors: Jinwoo, Lee; Tanaka, Hajime;

Local non-equilibrium thermodynamics

Abstract

AbstractLocal Shannon entropy lies at the heart of modern thermodynamics, with much discussion of trajectory-dependent entropy production. When taken at both boundaries of a process in phase space, it reproduces the second law of thermodynamics over a finite time interval for small scale systems. However, given that entropy is an ensemble property, it has never been clear how one can assign such a quantity locally. Given such a fundamental omission in our knowledge, we construct a new ensemble composed of trajectories reaching an individual microstate and show that locally defined entropy, information and free energy are properties of the ensemble, or trajectory-independent true thermodynamic potentials. We find that the Boltzmann-Gibbs distribution and Landauer's principle can be generalized naturally as properties of the ensemble and that trajectory-free state functions of the ensemble govern the exact mechanism of non-equilibrium relaxation.

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Keywords

Statistical Mechanics (cond-mat.stat-mech), Biological Physics (physics.bio-ph), Soft Condensed Matter (cond-mat.soft), FOS: Physical sciences, Physics - Biological Physics, Condensed Matter - Soft Condensed Matter, Condensed Matter - Statistical Mechanics, Article

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    popularity
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    Top 10%
    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
12
Top 10%
Average
Average
Green
gold