AbstractThe structure of materials with a negative electric susceptibility has been determined. Their electrical properties correspond to vanishing static dielectric permittivity. We give a theoretical explanation of anomalous polarization of powders observed in experiments and the mechanism of emergence in an aerosol cloud of an electric field, which is responsible for spark discharges (lightnings). We also explain the ball lightning properties known from observations. A fundamental scientific problem has been solved and the grounds have been laid for applications of new principles in electronics and electrical engineering.