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</script>doi: 10.1038/nmat1485
pmid: 16170320
Ferroelectric ceramics are widely used as sensors and actuators for their electro-mechanical properties, and in electronic applications for their dielectric properties. Domain switching--the phenomenon wherein the ferroelectric material changes from one spontaneously polarized state to another under electrical or mechanical loads--is an important attribute of these materials. However, this is a complex collective process in commercially used polycrystalline ceramics that are agglomerations of a very large number of variously oriented grains. As the domains in one grain attempt to switch, they are constrained by the differently oriented neighbouring grains. Here we use a combined theoretical and experimental approach to establish a relation between crystallographic symmetry and the ability of a ferroelectric polycrystalline ceramic to switch. In particular, we show that equiaxed polycrystals of materials that are either tetragonal or rhombohedral cannot switch; yet polycrystals of materials where these two symmetries co-exist can in fact switch.
Models, Molecular, Ceramics, Compressive Strength, Iron, Molecular Conformation, 530, Elasticity, 620, Models, Chemical, Materials Testing, Electrochemistry, Computer Simulation, Stress, Mechanical, Crystallization
Models, Molecular, Ceramics, Compressive Strength, Iron, Molecular Conformation, 530, Elasticity, 620, Models, Chemical, Materials Testing, Electrochemistry, Computer Simulation, Stress, Mechanical, Crystallization
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