Effects of Solvents on Acetylcholine Conformation

descriptionPublicationkeyboard_double_arrow_right Article 01 Aug 1966 English Publisher:Springer Science and Business Media LLCJournal:Nature, volume 211, pages 848-850 (issn: 0028-0836, eissn: 1476-4687,

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Authors: J H, Fellman; T S, Fujita;

doi: 10.1038/211848b0

pmid: 5968756

Effects of Solvents on Acetylcholine Conformation

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Abstract

IN earlier communications1–3 we reported the results of our investigations with acetylcholine and related substances. These led us to conclude that the acetyl group is activated primarily by an inductive influence of the quaternary nitrogen. This conclusion was based in large measure on the carbonyl stretching frequencies which were observed for acetylcholine and its homologues in ethanol, as well as on their rates of hydroxylaminolysis in water.

Related Organizations

University of Oregon
United States

Keywords

Magnetic Resonance Spectroscopy, Chemical Phenomena, Ethanol, Chemistry, Physical, Infrared Rays, Spectrophotometry, Dimethyl Sulfoxide, Deuterium, Acetylcholine

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