A Selectivity Reversal in Solvent Extraction

descriptionPublicationkeyboard_double_arrow_right Article 01 Nov 1963 English Publisher:Springer Science and Business Media LLCJournal:Nature, volume 200, pages 465-466 (issn: 0028-0836, eissn: 1476-4687,

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Authors: D. S. FLETT;

doi: 10.1038/200465a0

A Selectivity Reversal in Solvent Extraction

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Abstract

DURING an investigation of the extractive separation of cadmium and zinc with naphthenic acid1,2 a selectivity reversal has been observed on the changing of the supporting electrolyte anion from sulphate to chloride. This communication reports the results of a preliminary study of the system and comments on the possibility of measurement of formation constants of the inorganic ion association complexes in the aqueous phase by an extractive technique.

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