Powered by OpenAIRE graph
Found an issue? Give us feedback
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Naturearrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Nature
Article . 1963 . Peer-reviewed
License: Springer TDM
Data sources: Crossref
versions View all 1 versions
addClaim

Reaction of Phenyl Isocyanate with 2,3-Epoxy Propyl Phenyl Ether (Phenyl Glycidyl Ether)

Authors: D. A. SMITH;

Reaction of Phenyl Isocyanate with 2,3-Epoxy Propyl Phenyl Ether (Phenyl Glycidyl Ether)

Abstract

REACTION of phenyl isocyanate and 2,3-epoxy propyl phenyl ether gives a one-to-one addition compound, and there is evidence to suggest this is 3 phenyl 5 phenoxy methyl 2 oxazolidono. The reaction is believed to be: This is similar to a reaction reported by A. Thompson1 between acidulated potassium cyanate and epichlorhydrin. Evidence for the foregoing scheme is: (1) Reaction with alcoholic potash yielded a compound in agreement with the reaction: The product of this reaction gave a yellow oil on reaction with nitrous acid, suggesting a secondary amine. (2) There was no reaction of the reaction product with nitrous acid. The nitrogen of this compound is thus not present in the form of a primary or secondary amine. (3) The product of the reaction was broken down by heating with concentrated hydrochloric acid in a sealed tube at 200° C to give an oil, which was shown to be a chlorine containing compound. This is in agreement with the concept of acid hydrolysis of the oxazolidone ring.

Related Organizations
  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    3
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
3
Average
Average
Average
Upload OA version
Are you the author of this publication? Upload your Open Access version to Zenodo!
It’s fast and easy, just two clicks!