Infra-Red Frequency Shifts

descriptionPublicationkeyboard_double_arrow_right Article 09 Jul 1960 English Publisher:Springer Science and Business Media LLCJournal:Nature, volume 187, pages 142-142 (issn: 0028-0836, eissn: 1476-4687,

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Authors: R. S. NORRISH;

doi: 10.1038/187142a0

Infra-Red Frequency Shifts

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Abstract

THE effect of liquefaction and solution in different solvents on infra-red group frequencies has previously been considered in terms of changes in dielectric constant and postulated local association effects (for example, Caldow and Thompson1, and Bellamy and Williams2). A more fundamental approach would seem to be to relate the shifts to the actual solute-solution interaction energy.

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