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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Nature
Article . 1940 . Peer-reviewed
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Parahydrogen Conversion on Tungsten

Authors: D. D. ELEY; E. K. RIDEAL;

Parahydrogen Conversion on Tungsten

Abstract

THIS reaction1 has been reinvestigated using a reaction tube containing a second short filament adjacent to the catalyst filament, so that adsorbed films on the latter might be detected by a measurement of their contact potential2. In this way it was shown that the filament in its most catalytically active state was free from adsorbed oxygen. Under these conditions, as J. K. Roberts3 has pointed out, the clean wire on exposure to gaseous H2 takes up a stable film of hydrogen, which does not evaporate appreciably at room temperature, and so cannot give a para H2 conversion by the mechanism suggested by Farkas1, namely by H2+2W ⇄ 2WH (where W indicates a surface atom of tungsten). It is, however, possible4 that the conversion might occur by a surface interchange reaction of the type pH2 + WH → 0H2+ HW, and this mechanism gains support from the following experiment.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
168
Top 10%
Top 1%
Average
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