Thermodynamics of α-Cyclodextrin Complexation with Bases of Nucleic Acids and Their Derivatives

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2003 English Publisher:Springer Science and Business Media LLCJournal:Russian Journal of Coordination Chemistry, volume 29, pages 73-75 (issn: 1070-3284, eissn: 1608-3318,

Authors: I. V. Terekhova; Oleg V. Kulikov; P. V. Lapshev;

doi: 10.1023/a:1021803303379

Thermodynamics of α-Cyclodextrin Complexation with Bases of Nucleic Acids and Their Derivatives

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Abstract

The interactions of α-cyclodextrin with adenine, thymine, uracil, cytosine, and caffeine in water at 298.15 K have been studied by the calorimetric method. α-Cyclodextrin is found to interact selectively with nucleic bases and their derivatives to form complexes with uracil, cytosine, and caffeine only. The influence of the structure and solvation of the reactants on the thermodynamic characteristics of their complexation in a solution has been examined.

Related Organizations

Institute of Solution Chemistry
Russian Federation
Russian Academy of Sciences
Russian Federation
Department of Chemistry and Material Sciences
Russian Federation

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