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Article . 2004 . Peer-reviewed
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Organic Letters
Article . 2004 . Peer-reviewed
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Organic Letters
Article . 2005
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Total Synthesis of (−)-Reveromycin A

descriptionPublicationkeyboard_double_arrow_right Article 22 Jul 2004 English Publisher:American Chemical Society (ACS)Journal:Organic Letters, volume 6, pages 3,001-3,004 (issn: 1523-7060, eissn: 1523-7052, Copyright policy )
Authors: El Sous, Mariana; Ganame, Danny; Tregloan, Peter A.; Rizzacasa, Mark A.;

doi: 10.1021/ol048811l , 10.1002/chin.200450192

pmid: 15330668

Total Synthesis of (−)-Reveromycin A

Abstract

The asymmetric total synthesis of (-)-reveromycin A is described. The key steps involved a Lewis acid catalyzed inverse electron demand hetero-Diels-Alder reaction followed by hydroboration/oxidation to afford the spiroketal core 4 in a highly stereoselective manner and introduction of the C18 hemisuccinate by high-pressure acylation.

Related Organizations
Keywords

Molecular Structure, Organic chemistry, Combinatorial Chemistry Techniques, Indicators and Reagents, Spiro Compounds, Stereoisomerism, 03 Chemical Sciences, 0305 Organic Chemistry, Streptomyces, Pyrans

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
24
Average
Top 10%
Average