Palladium-Catalyzed Allylation of Imines with Allyl Alcohols

descriptionPublicationkeyboard_double_arrow_right Article 21 Jan 2005 English Publisher:American Chemical Society (ACS)Journal:Organic Letters, volume 7, pages 637-640 (issn: 1523-7060, eissn: 1523-7052,

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Authors: Masamichi, Shimizu; Masanari, Kimura; Toshiya, Watanabe; Yoshinao, Tamaru;

doi: 10.1021/ol047609f

pmid: 15704913

Palladium-Catalyzed Allylation of Imines with Allyl Alcohols

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Abstract

A catalytic system, Pd(OAc)2 (10 mol %)-P(n-Bu)3 (20 mol %)-Et3B (360 mol %), promotes allylic alcohols to undergo the allylation of anisidine-imines of aromatic and aliphatic aldehydes and furnishes homoallylamines in good to moderate yields. The reaction shows unique stereoselectivity, giving anti-isomers selectively. [reaction: see text]

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Nagasaki University
Japan
Nagasaki University
Japan

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