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ACS Nano
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ACS Nano
Article . 2013 . Peer-reviewed
Data sources: Crossref
https://dx.doi.org/10.48550/ar...
Article . 2013
License: arXiv Non-Exclusive Distribution
Data sources: Datacite
ACS Nano
Article . 2013
ACS Nano
Article . 2013
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Calibrating and Controlling the Quantum Efficiency Distribution of Inhomogeneously Broadened Quantum Rods by Using a Mirror Ball

Authors: Freddy T. Rabouw; Relinde J. A. van Dijk-Moes; Daniel Vanmaekelbergh; A. Femius Koenderink; Per Lunnemann; Francesca Pietra;

Calibrating and Controlling the Quantum Efficiency Distribution of Inhomogeneously Broadened Quantum Rods by Using a Mirror Ball

Abstract

We demonstrate that a simple silver coated ball lens can be used to accurately measure the entire distribution of radiative transition rates of quantum dot nanocrystals. This simple and cost-effective implementation of Drexhage's method that uses nanometer-controlled optical mode density variations near a mirror, not only allows to extract calibrated ensemble-averaged rates, but for the first time also to quantify the full inhomogeneous dispersion of radiative and non radiative decay rates across thousands of nanocrystals. We apply the technique to novel ultra-stable CdSe/CdS dot-in-rod emitters. The emitters are of large current interest due to their improved stability and reduced blinking. We retrieve a room-temperature ensemble average quantum efficiency of 0.87+-0.08 at a mean lifetime around 20 ns. We confirm a log-normal distribution of decay rates as often assumed in literature and we show that the rate distribution-width, that amounts to about 30% of the mean decay rate, is strongly dependent on the local density of optical states.

Keywords

DYNAMICS, FOS: Physical sciences, quantum dots, Sulfides, quantum rods, Quantum Dots, Mesoscale and Nanoscale Physics (cond-mat.mes-hall), BLINKING, Cadmium Compounds, Particle Size, Selenium Compounds, Lenses, DOTS, quantum efficiency, Condensed Matter - Mesoscale and Nanoscale Physics, decay-rate distribution, Equipment Design, Drexhage, Nanostructures, Equipment Failure Analysis, SPONTANEOUS EMISSION RATE, Quantum Theory, optical density of states, GAIN, nanorods, Physics - Optics, Optics (physics.optics)

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    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
29
Top 10%
Top 10%
Top 10%
Green
bronze