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Nano Letters
Article . 2008
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Nano Letters
Article . 2008 . Peer-reviewed
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Nano Letters
Article . 2008
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Reappraisal of Variable-Range Hopping in Quantum-Dot Solids

Authors: Houtepen, A.J.; Kockmann, D.; Vanmaekelbergh, D.A.M.;

Reappraisal of Variable-Range Hopping in Quantum-Dot Solids

Abstract

The temperature dependence of the electrical conductivity of assemblies of ZnO nanocrystals, studied with an electrochemically gated transistor is very accurately described by the relation ln sigma=ln sigma0-(T0/T)(x) with x=2/3 over the entire temperature range from 7 to 200 K, independent of charge concentration and dielectric environment. These results cannot be explained by existing models but are supported by results on Au nanocrystals where an identical temperature dependence was observed (Zabet-Khosousi et al., Phys. Rev. Lett. 2006, 96 (15), 156403). We propose an adaptation of the Efros-Shklovskii variable-range hopping model by introducing an expression for nonresonant tunneling based on local energy fluctuations, which yields exactly the temperature dependence that is observed experimentally.

Country
Netherlands
Related Organizations
Keywords

Quantum Dots, Electrochemistry, Normal Distribution, Temperature, Nanoparticles, Nanotechnology, Electrons, Equipment Design, Electronics, Models, Theoretical, Zinc Oxide

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
77
Top 10%
Top 10%
Top 10%
Green
bronze