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Reduced Auger Recombination in Single CdSe/CdS Nanorods by One-Dimensional Electron Delocalization

Authors: Per Lunnemann; Relinde J. A. van Dijk-Moes; Martin Frimmer; Freddy T. Rabouw; Francesca Pietra; Daniel Vanmaekelbergh; A. Femius Koenderink;

Reduced Auger Recombination in Single CdSe/CdS Nanorods by One-Dimensional Electron Delocalization

Abstract

Progress to reduce nonradiative Auger decay in colloidal nanocrystals has recently been made by growing thick shells. However, the physics of Auger suppression is not yet fully understood. Here, we examine the dynamics and spectral characteristics of single CdSe-dot-in-CdS-rod nanocrystals. These exhibit blinking due to charging/discharging, as well as trap-related blinking. We show that one-dimensional electron delocalization into the rod-shaped shell can be as effective as a thick spherical shell at reducing Auger recombination of the negative trion state.

Keywords

FLUORESCENCE INTERMITTENCY, trion, Nanocrystal, nanorod, CORE-SHELL NANOCRYSTALS, Auger recombination, COLLOIDAL NANOCRYSTALS, PHOTOLUMINESCENCE SPECTROSCOPY, colloidal quantum dot, SEEDED GROWTH, SEMICONDUCTOR NANOCRYSTALS, NANOCRYSTAL QUANTUM DOTS, blinking, DECAY, HETERONANOCRYSTALS, SUPPRESSED BLINKING

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    75
    popularity
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    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
75
Top 10%
Top 10%
Top 10%
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