
doi: 10.1021/nl4027567
pmid: 24010869
Progress to reduce nonradiative Auger decay in colloidal nanocrystals has recently been made by growing thick shells. However, the physics of Auger suppression is not yet fully understood. Here, we examine the dynamics and spectral characteristics of single CdSe-dot-in-CdS-rod nanocrystals. These exhibit blinking due to charging/discharging, as well as trap-related blinking. We show that one-dimensional electron delocalization into the rod-shaped shell can be as effective as a thick spherical shell at reducing Auger recombination of the negative trion state.
FLUORESCENCE INTERMITTENCY, trion, Nanocrystal, nanorod, CORE-SHELL NANOCRYSTALS, Auger recombination, COLLOIDAL NANOCRYSTALS, PHOTOLUMINESCENCE SPECTROSCOPY, colloidal quantum dot, SEEDED GROWTH, SEMICONDUCTOR NANOCRYSTALS, NANOCRYSTAL QUANTUM DOTS, blinking, DECAY, HETERONANOCRYSTALS, SUPPRESSED BLINKING
FLUORESCENCE INTERMITTENCY, trion, Nanocrystal, nanorod, CORE-SHELL NANOCRYSTALS, Auger recombination, COLLOIDAL NANOCRYSTALS, PHOTOLUMINESCENCE SPECTROSCOPY, colloidal quantum dot, SEEDED GROWTH, SEMICONDUCTOR NANOCRYSTALS, NANOCRYSTAL QUANTUM DOTS, blinking, DECAY, HETERONANOCRYSTALS, SUPPRESSED BLINKING
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