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pmid: 25658134
We show that an imbalance between the populations of singlet (S) and triplet (T) states in pairs of magnetically equivalent spins can be generated by dissolution dynamic nudear polarization: In partly deuterated ethanol ((CD3CH2OD)-C-13), this T/S imbalance can be transferred by cross-relaxation to observable, enhanced signals of protons and coupled C-13.
Carbon Isotopes, Magnetic Resonance Spectroscopy, Ethanol, Temperature, Protons, [CHIM.ORGA] Chemical Sciences/Organic chemistry
Carbon Isotopes, Magnetic Resonance Spectroscopy, Ethanol, Temperature, Protons, [CHIM.ORGA] Chemical Sciences/Organic chemistry
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