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On The Cavitation and Pore Blocking in Cylindrical Pores with Simple Connectivity

Authors: Nguyen, Phuong T. M.; Do, D. D.; Nicholson, D.;

On The Cavitation and Pore Blocking in Cylindrical Pores with Simple Connectivity

Abstract

We present a grand canonical Monte Carlo (GCMC) simulation of argon adsorption in connected cylindrical pores at 87.3 K. A number of pore models are constructed from various components: finite cylinder, finite cone, and flat surface. In the case of two cylinders of different sizes connected to each other with open ends, the adsorption isotherm can be described by a combination of two independent pores, the smaller of which is opened at both ends while the larger one is closed at one end. The adsorption isotherm depends on the relative size between the two sections of the connected pore. In the case of a cavity connected to the bulk surrounding gas via one or two narrower cylindrical necks, the phenomenon of either pore blocking or cavitation is observed, depending on the relative size between the neck and the cavity. If the neck size is smaller than a critical size, D(c), we observe cavitation, while pore blocking is observed when it is greater than D(c). This is due to the dominance of one of two mechanisms for removal of the adsorbates: either the receding of the menisci or the stretching of the fluid in the cavity. We also explore the effects of neck length and cavity length on the adsorption isotherm and conclude that while the neck length has a negligible effect on cavitation, it is of considerable importance when pore blocking occurs, because this process is controlled by the formation and movement of the meniscus in the pore neck. The effect of cavity length is found to be negligible in both cases.

Country
Australia
Keywords

Desorption branch, Nitrogen sorption isotherm, 2508 Surfaces, Coatings and Films, 541, Coatings and Films, 2508 Surfaces, Distributions, Adsorption, 1606 Physical and Theoretical Chemistry, 2505 Materials Chemistry

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
47
Top 10%
Top 10%
Top 10%
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