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The Journal of Organic Chemistry
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The Journal of Organic Chemistry
Article . 2011 . Peer-reviewed
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The Journal of Organic Chemistry
Article . 2012
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https://dx.doi.org/10.1021/jo2...
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Metal-Free Chlorodeboronation of Organotrifluoroborates

descriptionPublicationkeyboard_double_arrow_right Article 03 Aug 2011 English Publisher:American Chemical Society (ACS)Journal:The Journal of Organic Chemistry, volume 76, pages 7,195-7,203 (issn: 0022-3263, eissn: 1520-6904, Copyright policy )
Authors: Gary A, Molander; Livia N, Cavalcanti;

doi: 10.1021/jo201313a

pmid: 21812468

pmc: PMC3162988

Metal-Free Chlorodeboronation of Organotrifluoroborates

Abstract

A mild and metal-free method for the chlorodeboronation of organotrifluoroborates using trichloroisocyanuric acid (TCICA) was developed. Aryl-, heteroaryl-, alkenyl-, alkynyl-, and alkyltrifluoroborates were converted into the corresponding chlorinated products in good yields. This method proved to be tolerant of a broad range of functional groups.

Related Organizations
Keywords

Molecular Structure, Triazines, Borates, Fluorine, Chlorine

  • BIP!
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    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    		 74
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    		 Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    		 Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    		 Top 10%
Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
74
Top 10%
Top 10%
Top 10%
bronze