Clay−Fulleropyrrolidine Nanocomposites
Copyright policy )Clay−Fulleropyrrolidine Nanocomposites
In this work, we describe the insertion of a water-soluble bisadduct fulleropyrrolidine derivative into the interlayer space of three layered smectite clays. The composites were characterized by a combination of powder X-ray diffraction, transmission electron microscopy, X-ray photoemission and FTIR spectroscopies, and laser flash photolysis measurements. The experiments, complemented by computer simulations, give insight into the formation process, structural details, and properties of the fullerene/clay nanocomposites. The reported composite materials constitute a new hybrid system, where C(60) differs from its crystals or its solutions, and open new perspectives for the design and construction of novel C(60)-based organic/clay hybrid materials.
- University of Ioannina Greece
- Université de Namur Belgium
- University of Namur Belgium
- Alma Mater Studiorum University of Bologna Italy
- University of Groningen Netherlands
SMECTITE CLAYS, Pyrrolidines, SURFACE, energy minimization, smectite clays, EXCITED-STATE, ENERGY MINIMIZATION, Nanocomposites, c-60, SELF-ASSEMBLED MONOLAYERS, MCM-41 MATERIALS, Microscopy, Electron, Transmission, X-Ray Diffraction, excited-state, Spectroscopy, Fourier Transform Infrared, surface, Computer Simulation, self-assembled monolayers, azomethine ylides, FULLERENE DERIVATIVES, PILLARED CLAY, pillared clay, mcm-41 materials, AZOMETHINE YLIDES, fullerene derivatives, ", Clay, Aluminum Silicates, Fullerenes, C-60
SMECTITE CLAYS, Pyrrolidines, SURFACE, energy minimization, smectite clays, EXCITED-STATE, ENERGY MINIMIZATION, Nanocomposites, c-60, SELF-ASSEMBLED MONOLAYERS, MCM-41 MATERIALS, Microscopy, Electron, Transmission, X-Ray Diffraction, excited-state, Spectroscopy, Fourier Transform Infrared, surface, Computer Simulation, self-assembled monolayers, azomethine ylides, FULLERENE DERIVATIVES, PILLARED CLAY, pillared clay, mcm-41 materials, AZOMETHINE YLIDES, fullerene derivatives, ", Clay, Aluminum Silicates, Fullerenes, C-60
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