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Albumin-Conjugated Corrole Metal Complexes: Extremely Simple Yet Very Efficient Biomimetic Oxidation Systems

descriptionPublicationkeyboard_double_arrow_right Article 11 Feb 2005 English Publisher:American Chemical Society (ACS)Journal:Journal of the American Chemical Society, volume 127, pages 2,883-2,887 (issn: 0002-7863, eissn: 1520-5126, Copyright policy )
Authors: Atif, Mahammed; Zeev, Gross;

doi: 10.1021/ja045372c

pmid: 15740123

Albumin-Conjugated Corrole Metal Complexes: Extremely Simple Yet Very Efficient Biomimetic Oxidation Systems

Abstract

An extremely simple biomimetic oxidation system, consisting of mixing metal complexes of amphiphilic corroles with serum albumins, utilizes hydrogen peroxide for asymmetric sulfoxidation in up to 74% ee. The albumin-conjugated manganese corroles also display catalase-like activity, and mechanistic evidence points toward oxidant-coordinated manganese(III) as the prime reaction intermediate.

Related Organizations
Keywords

Manganese, Porphyrins, Sheep, Swine, Hydrogen Peroxide, Catalase, Oxygen, Biomimetic Materials, Animals, Humans, Oxidation-Reduction, Iron Compounds, Serum Albumin

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
244
Top 10%
Top 1%
Top 1%
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