Facile .alpha./.beta. diastereomerism in organocobalt corrinoids: synthesis, characterization, and complete proton and carbon-13 NMR assignments of .alpha.-5'-deoxyadenosylcobinamide and .alpha.-5'-deoxyadenosylcobalamin
Copyright policy ) Kenneth L. Brown; Xiang Zou;
Facile .alpha./.beta. diastereomerism in organocobalt corrinoids: synthesis, characterization, and complete proton and carbon-13 NMR assignments of .alpha.-5'-deoxyadenosylcobinamide and .alpha.-5'-deoxyadenosylcobalamin
Reductive alkylation of cobinamide in zinc/acetic acid with ether 5'-deoxy-5'-iodoadenosine or 5'-bromo-5'-deoxyadenosine has been found to produce a pair of diastereomeric 5'-deoxyadenosylcobinamides in which the deoxyadenosyl ligand is in the «upper» (or β) axial ligand position (β-AdoCbi) or in the «lower» (or α) axial ligand position (α-AdoCbi).
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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